Equilibrio de Fase 2015-2

8/18/2019 Equilibrio de Fase 2015-2

1/36

LN(Pi sat)=A-B/(T+C) A B C

Sustancia 1 16.59158 3643.31 -33.424

Sustancia 2 14.25326 2665.54 -53.424

P!S"#N B$B$%A 6&.&&3''8 1 &.1842&382

T (C) 318 2 &.815'9618

*1 &.25 i 1

P1sat(,Pa) 44.21P2sat(,Pa) 65.268

P!S"#N #C"# '.22!+&2' 1 &

T (C) 2 1

1 *i 1

P1sat(,Pa)

P2sat(,Pa)

T!P!AT$A B$B$%A !005&2 P1sat(,Pa) 3.5&'!+&54

P(,Pa) P2sat(,Pa) 1549216.69

1 1 "/& A70it7

T1sat !005&2 2 "/& 1) "nt07ucu:a 7s a

T2sat !005&2 i "/& 2) $s< s7a0a T7 T


2/36

Nu


3/36

7s; us< T


4/36

< an


5/36

LN(Psat)=A-B/(T+C) A B C

Sustancia 1 16.59158 3643.31 -33.424

Sustancia 2 14.25326 2665.54 -53.424 Aplica! al p"!#l$%a 10.1

2.&'70

1.0024

A=2.771-0.00'2&T 0.'00

P*S,N B*BA 47.707721 0.16042104

T (C) &4& 2 0.0&'7631 0.0' i 1

P1sat(5Pa) 7.00

P2sat(5Pa) 40.'00

P*S,N *C, 41.426417 1 0.007'2&761 Lu$! $ int"!uci" l!s at

T (C) &4& 2 0.1772244 N!ta< n! $s $l %is%! $su

1 0.04 3i 0.26006 Las Psat n! an iual a la

P1sat(5Pa) 7.00

P2sat(5Pa) 40.'00

2.'41

2ɣ 1.0001

T?P*AT*A B*BA &&1.14041 0.66417017

P(5Pa) 101.&& 2 0.&2206&&

1 0.' i 0.24602

T1sat (C) &&7.71& 77.&4'6&6

T2sat (C) &&0.07

T $sti%aa (C) &&1.000 Al!"it%!

A 1.0& 1) Lu$! $ int"!uci" l!s at!s su%inist"a!s8 usa"

1.02&7 2) sa" s!l;$" T!l$"ancia=0.001 ! :i=18 ;a"ian! T

2ɣ 2.11

LN(1)= A(

2)2

LN(2)= A(

1)2

ɣ1

ɣ1


6/36

A 1.010 A 1.062&' 1.010 1.0'7& 1.0'2

P1sat(5Pa) 0.4 P1sat(5Pa) 0.&'1'04 0.4 0.4 0.4

P2sat(5Pa) 11.114 P2sat(5Pa) 11.114 11.11 11.12 11.12@ 0.7'7'&11 @ 0.7'7'&111 0.7'7'&1 0.7'7'&1111 0.7'7'&1

31 0.44'472 31 0.241&'677 0.44'47& 0.&2'66114& 0.27'4&

32 0.''4'1271 32 0.7'064&2& 0.''4'127 0.674&&0'7 0.724'61

1.&67471& 1.41&4601 1.&67471 1.617&71767 1.74&1

2ɣ 1.224116' 2ɣ 1.0641'66 1.224116 1.11664221' 1.0&676'

Nu$;a P1sat (5Pa) 67.&146'67 Nu$;a P1sat ( 6'.&616'677 67.&146'7 66.276147 6'.1102

Nu$;a T (C) &27.66164 Nu$;a T (C) &26.6&6746 &27.6616' &27.&00&'1&2 &27.12612

T!l$"ancia .0&6 7.&&

AT*P

T (C) &4&

A 0.'00 1) D$"iEica" u$ $3ist$ un a>$!t"!p!

P1sat(5Pa) 7.00

P2sat(5Pa) 40.'

@128 31=0 '.040'7@128 31=1 0.76202&0'

1/ 2ɣ ɣ 0.'07'1

31 a> 0.'6'7

:1 a> 0.'6'7

1 a>ɣ 1.016272

P a>$!t"!p! 1.&66&077

ɣ1 ɣ1


7/36

!s8 $li9a una 31 l!ica : us$ s!l;$" pa"a 3i=18 ;a"ian! 31

$%a $ "$s!luci!n u$ $l $l $9$%pl! $l li#"!

$l li#"!8 ui>as $l li#"! t$na un $""!"

c!%! T $sti%aa inicial &&6.'6

$sti%aa8 c!n "$st"icci!n$s pa"a T $sti%aa $nt"$ l!s ;al!"$s $ T1sat : T2sat


8/36

1.0601 1.0606 1.060 1.060 1.060 1.060 1.060 1.060 1.060

0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4

11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12

0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1

0.2''4664 0.247'2&7 0.244&'4 0.24&07 0.242'4 0.242&42 0.242&142 0.242222 0.24226'

0.744'&&6 0.7'2476& 0.7''6406 0.7'6021 0.7'740'2 0.7'760' 0.7'76' 0.7'7717 0.7'77&0'

1.77764 1.2&02 1.&2'426 1.&6&42 1.&76& 1.&47 1.&7122 1.&0 1.&474

1.0716&7 1.0671& 1.06'&06 1.0647011 1.0644272 1.064&12 1.0642747 1.0642'74 1.0642'0'

6'.'6746 6'.46106 6'.417206 6'.&476 6'.&2&67 6'.&'26 6'.&&2 6'.&7& 6'.&77'

&27.0&06 &26.6& &26.&77 &26.77&6 &26.747 &26.7&76 &26.7&&' &26.7&1 &26.7&12


9/36


10/36

1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624

0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4

11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12

0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1

0.2422644 0.24206& 0.241'6 0.241''1 0.2414&& 0.241&6 0.241&6 0.241&61 0.241&'

0.7'77&'6 0.7'7&62 0.7'0144 0.7'044 0.7'0'67 0.7'0614 0.7'06&2 0.7'06& 0.7'0641

1.40&71' 1.40661 1.411 1.412& 1.41&2&' 1.41&&7& 1.41&426 1.41&447 1.41&4''

1.064&&7 1.0642271 1.06414& 1.0641676 1.0641611 1.0641'6 1.0641'76 1.0641'72 1.0641'71

6'.&6'& 6'.&6&&44 6'.&62&14 6'.&611& 6'.&617'7 6'.&6166 6'.&61672 6'.&6166& 6'.&616'

&26.6'24 &26.642 &26.6&1 &26.6&77 &26.6&71 &26.6&6 &26.6&6 &26.6&6 &26.6&6


11/36


12/36

1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624

0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4

11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12

0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1

0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7

0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064&

1.41&4' 1.41&4' 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46

1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7

6'.&616' 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7

&26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67


13/36


14/36

1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624

0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4

11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12

0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1

0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7

0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064&

1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46

1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7

6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7

&26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67


15/36


16/36

1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624

0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4

11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12

0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1

0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7

0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064&

1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46

1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7

6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7

&26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67


17/36


18/36

1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624

0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4

11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12

0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1

0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7

0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064&

1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46

1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7

6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7

&26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67


19/36


20/36

1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624

0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4

11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12

0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1

0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7

0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064&

1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46

1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7

6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7

&26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67


21/36


22/36

1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624

0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4

11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12

0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1

0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7

0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064&

1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46

1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7

6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7

&26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67


23/36


24/36

1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624

0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4

11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12

0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&10.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7

0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064&

1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46

1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7

6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7

&26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67


25/36


26/36

1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624

0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4

11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12

0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&10.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7

0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064&

1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46

1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7

6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7

&26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67


27/36


28/36

1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624 1.0624

0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4

11.12 11.12 11.12 11.12 11.12 11.12 11.12 11.12

0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&1 0.7'7'&10.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7 0.241&'7

0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064& 0.7'064&

1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46 1.41&46

1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7 1.0641'7

6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7 6'.&616'7

&26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67 &26.6&67


29/36

F!9a $ calcul! $ p"!#l$%as $ $uili#"i!

C**LAC,NS 5 = E(T8P)

P(Psia) 2'0 Trocio Tburbuja Tmezcla V

T(0F) 120.0 60.0 7.0 0.6941525

sp$ci$ i Gi i=i/Gi Gi i=Gii Gi i=GHii 3i=:i/Gi

%$tan! 0.100 10.000 0.010 &.000 0.&00 &.'00 0.12 0.0&7

$ltil$n! 0.400 2.00 0.14& 0.00 0.&60 1.1'0 0.417 0.&62

$tan! 0.'00 0.20 0.610 0.60 0.&40 0.760 0.4'6 0.600

ss 0.000 0.000Σ 1.000 0.76& 1.000 1.001 0.

:i 3i

&.4

T(0F) 2'0 Procio Pburbuja 0 V

P(Psia) '0.0 72'.0 620.0 0.2295516

sp$ci$ i Gi i=i/Gi Gi i=Gii Gi i=GHii 3i=:i/Gi

$tan! 0.400 &.000 0.1&& 1.00 0.760 2.00 0.0 0.27

p"!pan! 0.&00 1.1'0 0.261 0.'60 0.16 0.100 0.0& 0.&7

is!#utan! 0.&00 0.46 0.60' 0.240 0.072 0.4'0 0.1'' 0.&4&

0.000 0.000

Σ 1.000 Σxi= 1.000 Σyi= 1.000 1.000 1.000

:i 3i

1 2P int$"p!laa

P -4' -47 -4.2'0Σi= 1.01& 1.00'


30/36

0 0.1 0.2 0.& 0.4 0.' 0.6 0.7 0. 0. 1

60

6'

70

7'

0

'

0

'

100

Equilibrio Beceo!"#ua a 101.$$ %Pa

&1'1

T(o)


31/36

0 0.1 0.2 0.& 0.4 0.' 0.6 0.7 0. 0. 1

60

70

0

0

100

110

120

1&0

140

1'0

160

Equilibrio 1!lorobu*ao!lorobeceo a 90 %Pa

&1'1

T(o)


32/36

0 0.1 0.2 0.& 0.4 0.' 0.6 0.7 0. 0. 1

0

20

40

60

0

100

120

140

Equilibrio 1!lorobu*ao!lorobeceo a 90 0

P-

1

&!

P(%Pa)


33/36

0 0.1 0.2 0.& 0.4 0.' 0.6 0.7 0. 0. 1

60

70

0

0

100

110

120

1&0

140

1'0

160

Equilibrio Beceo!E*ilbeceo a 90 %Pa

&1'1

T(o)


34/36

0 0.1 0.2 0.& 0.4 0.' 0.6 0.7 0. 0. 1

'0

70

0

110

1&0

1'0

170

10

+ia#rama ,e Equilibrio Beceo!Tolueo

1

&1'1

P


35/36

0 0.1 0.2 0.& 0.4 0.' 0.6 0.7 0. 0.) 1

2'

27

2)

&1

&&

&'

&7

&)

+a*os equilibrio "ce*oi*rilo!Beceo

45

P-

1

P-31

&1'1

P (-Pa)


36/36

0 0.1 0.2 0.& 0.4 0.' 0.6 0.7 0. 0.) 1

2'

&'

4'

''

6'

7'

'

)'

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Equilibrio de Fase 2015-2

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