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    03-03-99 The Callendar - van Dusen coef f icients.doc RS 1/3

    0,00

    5,00

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    15,00

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    25,00

    30,00

    35,00

    -2

    00

    -1

    00 0

    1

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    2

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    3

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    4

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    8

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    The Callendar van Dusen coefficients

    The platinum thermometer is one of the most linear and practical temperature transdu-

    cers in existance. Yet it is still necessary to linearise the measured signal, as w ill appearfrom the diagram below . The diagram illustrates the disparity in ohms betw een the ac-

    tual resistance value at a given temperature and the value that w ould be obtained by asimple linear calculation for a Pt100 sensor:

    According to IEC751, the non-linearity of the platinum thermometer can be expressedas:

    ])100(CBA1[ 320 ttttRRt +++= (1)

    in which C is only applicable when t < 0 C.

    The coefficients A, B, and C for a standard sensor are stated in IEC751. If a standardsensor is not available or if a greater accuracy is required than can be obtained from the

    coefficients in the standard, the coefficients can be measured individually for each sen-sor. This can be done e.g. by determining the resistance value at a number of known

    temperatures and then determining the coefficients A, B, and C by regression analysis.

    The Callendar van Dusen method:

    However, an alternative method for determination of these coeff icients exists. Thismethod is based on the measuring of 4 known temperatures:

    Measure R0 at t0 = 0 C (the freezing point of w ater)

    Measure R100 at t100 = 100 C (t he boiling point of w at er)

    Figur 1. Deviat ion in ohms betw een the actual resistance value

    and the linear interpolation as a function of the temperatureexpressed in C.

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    Measure Rh at th = a high temperature (e.g. the freezing point of zink, 419.53 C)

    Measure Rl at t l: = a low temperature (e.g. the boiling point of oxygen, -182.96 C)

    Calculation of :

    First the linear parameter is determined as the normalised slope between 0 and 100 C:

    0

    0100

    100 R

    RR

    = (2)

    If this rough approximation is enough, the resistance at other temperatures can be cal-

    culated as:

    tRRRt += 00 (3)

    and the temperature as a function of the resistance value as:

    =

    0

    0

    RRRt t (4)

    Calculation of :

    Callendar has established a better approximation by introducing a term of the second

    order, , into the function. The calculation of is based on the disparity between the

    actual temperature, th, and the temperature calculated in (4):

    ))(1( 10010 0

    0

    0

    hh

    hh

    tt

    R

    RtRt

    =

    (5)

    With the introduction of into the equation, the resistance value for positive temperatu-

    res can be calculated w ith great accuracy:

    ][ ))(1(100100

    00

    tttRRRt += (6)

    Calculation of :

    At negative temperatures (6) w ill still give a small deviat ion as shown in figure 1 (bot-

    tom curve). Van Dusen therefore introduced a term of the fourth order, , which is only

    applicable for t< 0 C. The calculation of is based on the disparity between the actualtemperature, t l, and the temperature that would result from employing only and :

    3

    0

    0

    ))(1(

    ))(1(

    100100

    10010 0][

    ll

    ll

    tt

    tt

    R

    RtR llt

    +

    =

    (7)

    With the introduction of both Callendar' s and van Dusen' s constant, the resistance va-

    lue can be calculated correctly for the entire temperature range, as long as one remem-

    bers to set = 0 for t> 0 C:

    ][3

    00 ))(1())(1(10010 0100100

    tttttRRRt += (8)

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    Conversion to A, B, and C:

    Equation (8) is the necessary tool for accurate temperature determination. However,

    seeing that the IEC751 coeff icients A, B, and C are more w idely used, it w ould be natu-

    ral to convert to these coefficients:Equation (1) can be expanded to:

    )CC100BA1( 4320 ttttRRt +++= (9)

    and by simple coefficient comparison with equation (8) the follow ing can be determined:

    100A

    += (10)

    2100B

    = (11)

    4100C

    = (12)

    As an example, t he table below shows both sets of coeff icients f or a Pt100 resistoraccording to the IEC751 and ITS90 scale:

    0,003850 A 3,908 x 10 -3

    1,4999 B -5,775 x 10 -7

    0,10863 C -4,183 x 10 -12

    990303 / RS