Destilacion Por Reflujo Total

7/26/2019 Destilacion Por Reflujo Total

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Laboratorio de Ingeniera Qumica III

INDICE

UNIVERSIDAD NACIONAL DEL CALLAOFACULTAD DE INGENIERA QUMICAESCUELA DE INGENIERA QUMICA

LABORATORIO DE INGENIERA QUMICA IIIDESTILACION POR REFLUJO TOTAL

PROFESOR:

MEDINA COLLANTES JUAN

INTEGRANTES:

ARAUJO VILLANUEVA, LESLY EMPERATRIZ 090096C

YANCE PICHIULE, MIRELLA KATERIN 070095A


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I. OBJETIVO..........................................................................................................3

II. MARCO TEORICO............................................................................................3

III. EQUIPOS Y MATERIALES................................................................................5

IV. PROCEDIMIENTO EXPERIMENTAL..................................................................6

V. DATOS EXPERIMENTALES Y CALCULOS.............................................................7

VI. CONCLUSIONES............................................................................................16

VII. RECOMENDACIONES.....................................................................................16

VIII. BIBLIORA!IAS........................................................................................16

DESTILACION POR REFL!O TOTAL


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I" O#!ETI$O

C"#$%#"& '# ()*'&+ *(-*+ /' #"1+ 1'2&-$+ " &'3#%4+ 1+1"# "&" %(" /'1-#"$-2(

/'# -1'*" '1"(+#"%". &"3-$"& '( $'*$"/ '# -1'*" '1"(+# 8 "%" "&" /-3'&'(1' *+/'#+.

II" %ARCO TEORICO

E# &+$'+ /' '"&"$-2( * %1-#-:"/+ '( #" -(/%1&-" ;%*-$" ' #" D'1-#"$-2(. E1"

+'&"$-2( %(-1"&-" 1"* /-?'&". E# +'(+ %&+ ;%' ' %1-#-:" '(

#" 3"


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$&%/+. E1" 3&"$$-+(' ' &+$'"( /'%= "&" + 3#%>' '( 3+&*" /'$'(/'(1' +& &"?'/"/. E( '# $"*-(+ 3#%>' " 1&"?= /'


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$"/" #"1+ > " 1&"?= /' %( $+(/%$1+, "# #"1+ -(3'&-+&. E# " "" "$-" "&&- '# #;%-/+,"%(;%' $"/" #"1+ ' $"&"$1'&-:" +& '# 3#%4+ 1&"(?'&"# /' #+ /+. C"/" #"1+ '( #"

1+&&' ' %(" '1"", %'1+ ;%' + #+ 3#%-/+ ' '"&"(.

E# ()*'&+ /' #"1+ 1'2&-$+ + '1"" '( '# ';%-#- +& #+ 1"(1+, '# ()*'&+ /' #"1+ &'"#' ' /'1'&*-(" +& '#/-'@+ *'$(-$+ %1-#-:"/+ > #" $+(/-$-+(' /' +'&"$-2(.

III" EQIPOS & %ATERIALES

E;%-+ /' $+#%*(" /' /'1-#"$-2(.Figura ':E(ui)o de co*umna de de+ti*aci,n"

Fuente: E*aboraci,n )ro)ia

&'3&"$12*'1&+.

Figura -: re.ract,metro"


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Fuente: E*aboraci,n )ro)ia

I$" PROCEDI%IENTO E/PERI%ENTAL

Se Prepara la e!"la #e 5L e$a%&l ' A()a al 3*+ e% ,&l)e%.

La "&%#-"-% #e $ra/a0& er a )%a $epera$)ra "&%$a%$e

ee0a%$e a la $epera$)ra #e e/)ll-"-% #el "&p&%e%$e

,&l$-l.

Se -#e la $epera$)ra e %#-"e #e rera""-% #e la e!"la e$a%&l

a()a.

e#-r ,&l)e% -%-"-al #e al"&&l #-l)-#& a #e$-lar.

Se $&ar )%a )e$ra #el &%#& a/r-e%#& la ,l,)la "er"a%a al

re/&-ler. C&% e$& %#-"e %& -re& al (r8"& ' allare& la

"&%"e%$ra"-&%e e% el $&pe ' e% el &%#&.


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$" DATOS E/PERI%ENTALES & CALCLOS

Dato+:

Tentrada 0-O1--234C

T+a*ida 0-O1-5254C

m13-66cm37min

P=65cmde agua

nR=1,3469

nD=1,371

0a**ando e* ca*or ganando

Q1mCe8T

QG

3200106

m3

min.1min.

60 s1000kg

1m3

1k cal

k g c(26,622,3 ) C

Q16"--9ca*7+1--923ca*7+

Tem)eratura en cada )*ato

T' ;94C

T- 7,C

T3 0,C

T< 0,C

T= 0,96C

T5 ,CT; ,9C

T> 9,6C

S' 1-'(' #+ -%-'(1' /"1+ >" '1"


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Tab*a '

Ethanol

Concentration v! re"ractive in#e$ %&'(C)

* +, -t! nD

'!'' 1.333*.!'' 1.336*

/'!'' 1.33:5

/.!'' 1.3432

&'!'' 1.346:

0'!'' 1.3535

1'!'' 1.3593

.'!'' 1.3616

2'!'' 1.3639

3'!'' 1.3652

4'!'' 1.3659

5'!'' 1.365*

/''!'' 1.3614

Senitivit,6 * *.*65*

C+( '1+ /"1+ +


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Gra.ica ': ndice de re.racci,n $+ ? etano*

1.33 1.34 1.34 1.35 1.35 1.36 1.36 1.37 1.37

*

1*

2*

3*

4*

5*

6*

7*

9*

:*

1**

in#i#ce #e re"raccion %n#)

*"raccion 7aa etanol

D' #" &3-$" 1'(-'(/+ '# (/-$' /' &'3&"$$-2( "##"/+ '( '# #"


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wR .=0.2318

P"&" '# /'1-#"/+

nD=1,371

wD .=84.905

wD .=0.8491

6"3910.8491

( RDmin.

+1)

RD

min.

=

'"';;-

0a**ando e* nmero mnimo de )*ato+

0aciendo *a gr.ica de* +i+tema etano*agua en e* c@emcad

%ODELO IDEAL

CHEMCAD 6.. P"'

J+< N"*' U(1-1#'/ D"1' 09505 T-*' 70

XY /"1" 3+& E1"(+# "1'&

K ?"#%' *+/'# VAP

M+#' !&"$1-+(

T D' C P "1* X Y 99.990 .00000 0.00000 0.00000

9.7 .00000 0.05000 0.065

96.765 .00000 0.0000 0.995.95 .00000 0.5000 0.7

9.990 .00000 0.0000 0.5509.5955 .00000 0.5000 0.76


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9.659 .00000 0.0000 0.90590.69 .00000 0.5000 0.576.999 .00000 0.0000 0.6007.97 .00000 0.5000 0.656.75 .00000 0.50000 0.69

5.9 .00000 0.55000 0.7.7799 .00000 0.60000 0.776

.997 .00000 0.65000 0.0.056 .00000 0.70000 0..950 .00000 0.75000 0.7.67 .00000 0.0000 0.900.569 .00000 0.5000 0.9979.76 .00000 0.90000 0.9560

79.0577 .00000 0.95000 0.977507.09 .00000 .00000 .00000

%ODELO NIFAC

CHEMCAD 6.. P"'

J+< N"*' U(1-1#'/ D"1' 09505 T-*' 56

XY /"1" 3+& E1"(+# "1'&


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K ?"#%' *+/'# UNI!AC

M+#' !&"$1-+( T D' C P "1* X Y "**" "**" P- P-

99.99 .000 0.00000 0.00000 6.75 .000 .000 .0009. .000 0.05000 0.50 .595 .00 .000 .000

5.0 .000 0.0000 0.505 . .05 .000 .000.0 .000 0.5000 0.9 .659 .07 .000 .000.05 .000 0.0000 0.5796 .97 .6 .000 .000. .000 0.5000 0.55077 .5 .66 .000 .000.79 .000 0.0000 0.57 .667 . .000 .000.9 .000 0.5000 0.5909 .509 . .000 .000

0.7 .000 0.0000 0.60 .9 .6 .000 .0000.6 .000 0.5000 0.6 .0 . .000 .000

79.57 .000 0.50000 0.655 . .5 .000 .00079.79 .000 0.55000 0.670 .7 .56 .000 .00079.7 .000 0.60000 0.700 .5 .6 .000 .0007. .000 0.65000 0.706 .0 .77 .000 .0007.57 .000 0.70000 0.7595 .07 .9 .000 .0007.55 .000 0.75000 0.7970 .05 .9 .000 .000

7.9 .000 0.0000 0.6 .0 .07 .000 .0007.06 .000 0.5000 0.590 .00 .7 .000 .000

7.05 .000 0.90000 0.990 .009 . .000 .0007. .000 0.95000 0.950 .00 .5 .000 .0007.09 .000 .00000 .00000 .000 .00 .000 .000


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%ODELO NIQAC

CHEMCAD 6.. P"'

J+< N"*' U(1-1#'/ D"1' 09605 T-*' 000

XY /"1" 3+& E1"(+# "1'&

UNIQUAC U-4U44 U4-U-- A-4 A4- C-4 C4- D-4 D4-

50. .0 0.00 0.00 0.00 0.00 0.00 0.00

M+#' !&"$1-+(

T D' C P "1* X Y "**" "**" P- P- 99.99 .000 0.00000 0.00000 5.60 .000 .000 .000

90.6 .000 0.05000 0.6 .0 .007 .000 .000

6.575 .000 0.0000 0.9 .9 .07 .000 .000.6 .000 0.5000 0.9 .6 .057 .000 .000

. .000 0.0000 0.50 .7 .095 .000 .000.77 .000 0.5000 0.5600 .9 . .000 .000.6 .000 0.0000 0.57 .705 .96 .000 .000.09 .000 0.5000 0.6007 .50 .56 .000 .0000.6 .000 0.0000 0.69 . . .000 .0000.6 .000 0.5000 0.67 .6 .95 .000 .000

79.7 .000 0.50000 0.6575 .9 .7 .000 .00079.90 .000 0.55000 0.6777 .7 .557 .000 .000

79.7 .000 0.60000 0.70 . .67 .000 .0007.9 .000 0.65000 0.77 .09 .7 .000 .0007.65 .000 0.70000 0.755 .06 . .000 .0007.5 .000 0.75000 0.7596 .0 .9 .000 .0007.0 .000 0.0000 0.0 .05 .059 .000 .0007.05 .000 0.5000 0.50 .0 .75 .000 .000

7.70 .000 0.90000 0.900 .006 .97 .000 .0007.0 .000 0.95000 0.970 .00 . .000 .000

7.09 .000 .00000 .00000 .000 .55 .000 .000


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$I" CONCLSIONES

L+&"*+ C"#$%#"& '# ()*'&+ /' #"1+ 1'2&-$+

L+&"*+ &"3-$"& '( $'*$"/ '# -1'*" '1"(+# 8 "%" "&" /-3'&'(1' *+/'#+

-/'"#, %(-3"$, %(-;%"$.

$II" RECO%ENDACIONES

E$%$"& #" -(/-$"$-+(' /'# &+3'+&.

1'('& $%-/"/+ $+( #" 1+&&' /' #"1+ >" ;%' - #+ %"*+ -("/'$%"/"*'(1' %'/'*"#+&"&'.

$III" #I#LIOGRAFIAS

T&'>

Destilacion Por Reflujo Total

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