Síntese de Catalisadores Microporosos

8/20/2019 Síntese de Catalisadores Microporosos

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ASAP 2020 V3.04 E Unit 1 Serial #: 1220 Page 1

Sample: Z-22- 15h_SAR90Operator: RAMIROSubmitter: MARITZA/OSIMAR

File: C:\2020\DATA\000-560.SMP

Started: 2/2/2016 11:15:32 Analysis Adsorptive: N2

Completed: 3/2/2016 9:01:19 Analysis Bath Temp.: -195.810 °C

Report Time: 2/3/2016 9:42:39 Thermal Correction: No

Sample Mass: 0.3206 g Warm Free Space: 16.3209cm³ Measured

Cold Free Space: 50.0869 cm³ Equilibration Interval: 45 s

Low Pressure Dose: None Automatic Degas: Yes

Summary Report

Surface Area

Single point surface area at P/Po = 0.100483567: 266.3034 m²/g

BET Surface Area: 264.4964 m²/g

Langmuir Surface Area: 314.3862 m²/g

t-Plot Micropore Area: 220.4223 m²/g

t-Plot External Surface Area: 44.0741 m²/g

BJH Adsorption cumulative surface area of poresbetween 17.000 Å and 3000.000 Å diameter: 45.373 m²/g

BJH Desorption cumulative surface area of poresbetween 17.000 Å and 3000.000 Å diameter: 43.5294 m²/g

Pore Volume

Single point adsorption total pore volume of poresless than 674.350 Å diameter at P/Po = 0.970450947: 0.248078 cm³/g

t-Plot micropore volume: 0.089035 cm³/g

BJH Adsorption cumulative volume of poresbetween 17.000 Å and 3000.000 Å diameter: 0.290055 cm³/g


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BJH Desorption cumulative volume of poresbetween 17.000 Å and 3000.000 Å diameter: 0.286577 cm³/g

Pore Size

Adsorption average pore width (4V/A by BET): 37.5170 Å

BJH Adsorption average pore diameter (4V/A): 255.709 Å

BJH Desorption average pore diameter (4V/A): 263.341 Å










Isotherm Tabular Report

QuantityRelative Absolute Adsorbed Elapsed SaturationPressure Pressure (cm³/g Time Pressure(P/Po) (mmHg) STP) (h:min) (mmHg)

-----

1.#QNAN0000 1.#QNAN0 1.#QNB 00:53 759.5661620.014081650 10.686584 64.2486 04:35 1.#QNAN01.#QNAN0000 1.#QNAN0 1.#QNB 04:38 758.8923950.020917007 15.875323 64.7956 05:00 1.#QNAN00.028172930 21.383768 65.2787 05:15 1.#QNAN00.032321348 24.534252 65.5339 05:31 1.#QNAN00.038825520 29.472977 65.7990 05:43 1.#QNAN00.044032361 33.427208 66.0807 05:54 1.#QNAN00.051300240 38.946545 66.4237 06:05 1.#QNAN00.057955399 44.001823 66.6594 06:19 1.#QNAN0


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0.063104639 47.913673 66.8708 06:30 1.#QNAN00.069374523 52.676353 67.1076 06:39 1.#QNAN01.#QNAN0000 1.#QNAN0 1.#QNB 06:42 759.3142090.075814497 57.569386 67.3086 06:51 1.#QNAN00.082442356 62.604786 67.5060 07:00 1.#QNAN00.088553094 67.247894 67.6531 07:09 1.#QNAN00.094544520 71.800446 67.8438 07:17 1.#QNAN00.100483567 76.313896 68.0079 07:26 1.#QNAN00.119598078 90.834450 68.4534 07:35 1.#QNAN00.141060717 107.140152 68.9106 07:45 1.#QNAN00.161372937 122.572403 69.3146 07:53 1.#QNAN00.181056702 137.529037 69.6784 08:02 1.#QNAN00.200686837 152.445465 70.0541 08:10 1.#QNAN00.249314851 189.392838 70.8598 08:20 1.#QNAN00.301604356 229.123077 71.6998 08:28 1.#QNAN00.351855740 267.309052 72.5002 08:37 1.#QNAN00.399949705 303.859070 73.2813 08:46 1.#QNAN01.#QNAN0000 1.#QNAN0 1.#QNB 08:48 759.7501220.449767644 341.719177 74.1378 08:57 1.#QNAN00.500139933 379.998505 75.0858 09:05 1.#QNAN00.550150032 418.005371 76.1414 09:14 1.#QNAN00.600076934 455.950836 77.3228 09:23 1.#QNAN00.649884501 493.808746 78.7359 09:33 1.#QNAN00.699894302 531.820923 80.4606 09:42 1.#QNAN0

0.749575588 569.586792 82.6502 09:52 1.#QNAN00.798986584 607.150879 85.6725 10:03 1.#QNAN00.821274204 624.105469 87.5000 10:14 1.#QNAN00.849835223 645.830200 90.5429 10:26 1.#QNAN00.874327095 664.465637 94.1184 10:39 1.#QNAN00.898591264 682.938354 99.2706 10:57 1.#QNAN01.#QNAN0000 1.#QNAN0 1.#QNB 10:59 760.0140380.922474978 700.859497 107.3492 11:18 1.#QNAN00.944334137 717.164063 121.0751 11:42 1.#QNAN00.970450947 736.375122 160.3813 12:30 1.#QNAN00.977413255 741.174377 177.7005 13:07 1.#QNAN01.#QNAN0000 1.#QNAN0 1.#QNB 13:08 758.2885740.984892357 746.456848 211.7228 14:03 1.#QNAN0

0.989507380 749.625122 243.3612 14:51 1.#QNAN00.987803174 748.251831 239.3748 15:03 1.#QNAN00.985880703 746.699829 233.3155 15:17 1.#QNAN01.#QNAN0000 1.#QNAN0 1.#QNB 15:19 757.3798220.979936787 742.372620 209.7094 15:55 1.#QNAN00.950358537 720.274353 137.2507 16:56 1.#QNAN01.#QNAN0000 1.#QNAN0 1.#QNB 17:29 758.0736080.923601148 700.283020 114.4062 17:48 1.#QNAN00.898701983 681.571167 103.2729 18:14 1.#QNAN00.872745465 662.004333 96.6051 18:33 1.#QNAN00.840025505 637.299255 91.4923 18:52 1.#QNAN00.815767303 618.971130 88.8491 19:05 1.#QNAN00.801684036 608.342590 87.5932 19:15 1.#QNAN0

0.748952470 568.392456 84.0803 19:27 1.#QNAN00.699865227 531.189331 81.8438 19:37 1.#QNAN01.#QNAN0000 1.#QNAN0 1.#QNB 19:39 759.0023190.651077955 494.169678 80.1532 19:48 1.#QNAN00.601117093 456.249268 78.7414 19:58 1.#QNAN00.550284975 417.667572 77.6264 20:07 1.#QNAN00.501222187 380.428802 76.6144 20:16 1.#QNAN00.450037128 341.579224 75.6850 20:25 1.#QNAN00.400498886 303.979584 74.8544 20:34 1.#QNAN00.349594958 265.343384 74.0968 20:43 1.#QNAN0


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0.300032271 227.725189 73.4035 20:52 1.#QNAN00.250198786 189.901459 72.6753 21:01 1.#QNAN00.200071666 151.854858 71.8879 21:09 1.#QNAN00.140121042 106.352196 70.8757 21:19 1.#QNAN0








Cold Free Space: 50.0869 cm³ Equilibration Interval: 45 sLow Pressure Dose: None Automatic Degas: Yes

Isotherm Linear Plot

Z-22- 15h_SAR90 - AdsorptionRelative Pressure (P/Po) Quantity Adsorbed (cm³/g STP)0.0140816 64.24860.020917 64.79560.0281729 65.27870.0323213 65.53390.0388255 65.7990.0440324 66.08070.0513002 66.42370.0579554 66.65940.0631046 66.87080.0693745 67.10760.0758145 67.3086

0.0824424 67.5060.0885531 67.65310.0945445 67.84380.100484 68.00790.119598 68.45340.141061 68.91060.161373 69.31460.181057 69.67840.200687 70.05410.249315 70.8598


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0.301604 71.69980.351856 72.50020.39995 73.28130.449768 74.13780.50014 75.08580.55015 76.14140.600077 77.32280.649885 78.73590.699894 80.46060.749576 82.65020.798987 85.67250.821274 87.50.849835 90.54290.874327 94.11840.898591 99.27060.922475 107.3490.944334 121.0750.970451 160.3810.977413 177.70.984892 211.7230.989507 243.361

Z-22- 15h_SAR90 - DesorptionRelative Pressure (P/Po) Quantity Adsorbed (cm³/g STP)

0.989507 243.3610.987803 239.3750.985881 233.3150.979937 209.7090.950359 137.2510.923601 114.4060.898702 103.2730.872745 96.60510.840026 91.49230.815767 88.84910.801684 87.59320.748952 84.08030.699865 81.8438

0.651078 80.15320.601117 78.74140.550285 77.62640.501222 76.61440.450037 75.6850.400499 74.85440.349595 74.09680.300032 73.40350.250199 72.67530.200072 71.88790.140121 70.8757





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Isotherm Log Plot

Z-22- 15h_SAR90 - AdsorptionRelative Pressure (P/Po) Quantity Adsorbed (cm³/g STP)

0.0140816 64.24860.020917 64.79560.0281729 65.27870.0323213 65.53390.0388255 65.7990.0440324 66.08070.0513002 66.42370.0579554 66.65940.0631046 66.87080.0693745 67.10760.0758145 67.30860.0824424 67.5060.0885531 67.6531

0.0945445 67.84380.100484 68.00790.119598 68.45340.141061 68.91060.161373 69.31460.181057 69.67840.200687 70.05410.249315 70.85980.301604 71.69980.351856 72.50020.39995 73.28130.449768 74.13780.50014 75.0858

0.55015 76.14140.600077 77.32280.649885 78.73590.699894 80.46060.749576 82.65020.798987 85.67250.821274 87.50.849835 90.54290.874327 94.11840.898591 99.2706


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0.922475 107.3490.944334 121.0750.970451 160.3810.977413 177.70.984892 211.7230.989507 243.361

Z-22- 15h_SAR90 - DesorptionRelative Pressure (P/Po) Quantity Adsorbed (cm³/g STP)0.989507 243.3610.987803 239.3750.985881 233.3150.979937 209.7090.950359 137.2510.923601 114.4060.898702 103.2730.872745 96.60510.840026 91.49230.815767 88.84910.801684 87.59320.748952 84.08030.699865 81.84380.651078 80.15320.601117 78.7414

0.550285 77.62640.501222 76.61440.450037 75.6850.400499 74.85440.349595 74.09680.300032 73.40350.250199 72.67530.200072 71.88790.140121 70.8757











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BET Surface Area Report

BET Surface Area: 264.4964 ± 1.1860 m²/gSlope: 0.016484 ± 0.000074 g/cm³ STP

Y-Intercept: -0.000026 ± 0.000005 g/cm³ STPC: -642.033737Qm: 60.7591 cm³/g STP

Correlation Coefficient: 0.9998803Molecular Cross-Sectional Area: 0.1620 nm²

QuantityRelative AdsorbedPressure (cm³/g 1/[Q(Po/P(P/Po) STP) - 1)]

--- 0.020917007 64.7956 0.0003300.028172930 65.2787 0.0004440.032321348 65.5339 0.0005100.038825520 65.7990 0.000614

0.044032361 66.0807 0.0006970.051300240 66.4237 0.0008140.057955399 66.6594 0.0009230.063104639 66.8708 0.0010070.069374523 67.1076 0.0011110.075814497 67.3086 0.0012190.082442356 67.5060 0.0013310.088553094 67.6531 0.0014360.094544520 67.8438 0.0015390.100483567 68.0079 0.001643











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BET Surface Area Plot

Z-22- 15h_SAR90Relative Pressure (P/Po) 1/[Q(Po/P - 1)]0.020917 0.0003297120.0281729 0.000444090.0323213 0.0005096740.0388255 0.0006138970.0440324 0.0006970340.0513002 0.0008140810.0579554 0.0009229130.0631046 0.001007240.0693745 0.001110850.0758145 0.001218770.0824424 0.001330990.0885531 0.00143610.0945445 0.001539070.100484 0.00164258










Langmuir Surface Area Report

Langmuir Surface Area: 314.3862 ± 1.0573 m²/gSlope: 0.013847 ± 0.000047 g/cm³ STP

Y-Intercept: 0.068618 ± 0.005468 mmHg·g/cm³ STPb: 0.201793 1/mmHg


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Qm: 72.2196 cm³/g STPCorrelation Coefficient: 0.999977

Molecular Cross-Sectional Area: 0.1620 nm²

QuantityAdsorbed P/Q

Pressure (cm³/g (mmHg·g/cm³(mmHg) STP) STP)

--- 76.313896 68.0079 1.122

90.834450 68.4534 1.327107.140152 68.9106 1.555122.572403 69.3146 1.768137.529037 69.6784 1.974152.445465 70.0541 2.176


Sample: Z-22- 15h_SAR90

Operator: RAMIROSubmitter: MARITZA/OSIMARFile: C:\2020\DATA\000-560.SMP







Langmuir Surface Area Plot

Z-22- 15h_SAR90

Pressure (mmHg) P/Q (mmHg·g/cm³ STP)76.3139 1.1221390.8344 1.32695107.14 1.55477122.572 1.76835137.529 1.97377152.445 2.17611


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t-Plot Report

Micropore Volume: 0.089035 cm³/gMicropore Area: 220.4223 m²/g

External Surface Area: 44.0741 m²/gSlope: 2.849370 ± 0.045674 cm³/g·Å STP

Y-Intercept: 57.560478 ± 0.189139 cm³/g STPCorrelation Coefficient: 0.999358

Surface Area Correction Factor: 1.000

Density Conversion Factor: 0.0015468Total Surface Area (BET): 264.4964 m²/gThickness Range: 3.5000 Å to 5.0000 Å

Thickness Equation: Harkins and Jura

t = [ 13.99 / ( 0.034 - log(P/Po) ) ] ^ 0.5

QuantityRelative Statistical AdsorbedPressure Thickness (cm³/g(P/Po) (Å) STP)

--- 0.100483567 3.6820 68.00790.119598078 3.8249 68.45340.141060717 3.9768 68.91060.161372937 4.1150 69.31460.181056702 4.2455 69.67840.200686837 4.3733 70.05410.249314851 4.6855 70.85980.301604356 5.0227 71.69980.351855740 5.3563 72.5002


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0.399949705 5.6908 73.28130.449767644 6.0595 74.13780.500139933 6.4632 75.08580.550150032 6.9038 76.14140.600076934 7.3954 77.32280.649884501 7.9534 78.7359





Completed: 3/2/2016 9:01:19 Analysis Bath Temp.: -195.810 °CReport Time: 2/3/2016 9:42:39 Thermal Correction: No




t-PlotHarkins and Jura

Z-22- 15h_SAR90Thickness (Å) Quantity Adsorbed (cm³/g STP)3.68204 68.00793.82488 68.45343.97683 68.91064.11504 69.31464.24547 69.6784

4.37328 70.05414.68547 70.8598

Not Fitted PointsThickness (Å) Quantity Adsorbed (cm³/g STP)5.02266 71.69985.35626 72.50025.69075 73.28136.05954 74.13786.46317 75.0858


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6.90384 76.14147.39545 77.32287.95338 78.7359








Cold Free Space: 50.0869 cm³ Equilibration Interval: 45 sLow Pressure Dose: None Automatic Degas: Yes

BJH Adsorption Pore Distribution Report

Faas Correction

Halseyt = 3.54 [ -5 / ln(P/Po) ] ^ 0.333

Diameter Range: 17.000 Å to 3000.000 ÅAdsorbate Property Factor: 9.53000 ÅDensity Conversion Factor: 0.0015468

Fraction of Pores Open at Both Ends: 0.00

Incremental CumulativeCumulative

Average Pore Pore Incremental

PorePore Diameter Diameter Volume Volume Pore AreaArea

Range (Å) (Å) (cm³/g) (cm³/g) (m²/g) (m²/g------ 1862.1 - 1300.8 1483.0 0.052322 0.052322 1.411

1.4111300.8 - 876.9 1007.4 0.056915 0.109237 2.2603.671876.9 - 674.4 748.8 0.029079 0.138315 1.553


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5.224674.4 - 364.1 431.2 0.068501 0.206816 6.354

11.579364.1 - 264.2 297.8 0.023599 0.230416 3.170

14.749264.2 - 203.7 225.7 0.013662 0.244078 2.421

17.170203.7 - 165.5 180.4 0.008560 0.252638 1.898

19.068165.5 - 139.3 149.9 0.005815 0.258453 1.551

20.620139.3 - 117.6 126.4 0.004860 0.263312 1.538

22.157117.6 - 104.8 110.4 0.002846 0.266158 1.031

23.188104.8 - 84.4 92.2 0.004604 0.270762 1.998

25.18784.4 - 70.5 76.0 0.003195 0.273957 1.682

26.86870.5 - 60.2 64.4 0.002447 0.276404 1.519

28.38860.2 - 52.5 55.7 0.001961 0.278365 1.408

29.79652.5 - 46.3 48.9 0.001561 0.279926 1.278

31.07346.3 - 41.2 43.4 0.001403 0.281330 1.29532.368

41.2 - 36.9 38.7 0.001224 0.282554 1.26433.632

36.9 - 33.3 34.8 0.001078 0.283632 1.23834.870

33.3 - 30.2 31.5 0.000982 0.284614 1.24636.116

30.2 - 27.3 28.5 0.001051 0.285665 1.47337.588

27.3 - 24.6 25.7 0.001172 0.286837 1.82239.410

24.6 - 22.2 23.2 0.001180 0.288017 2.03241.44222.2 - 21.3 21.7 0.000709 0.288726 1.307

42.74921.3 - 20.4 20.8 0.000601 0.289327 1.156

43.90520.4 - 19.4 19.8 0.000728 0.290055 1.467

45.373





Completed: 3/2/2016 9:01:19 Analysis Bath Temp.: -195.810


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°CReport Time: 2/3/2016 9:42:39 Thermal Correction: No




BJH Adsorption Cumulative Pore VolumeHalsey : Faas Correction

Z-22- 15h_SAR90Pore Diameter (Å) Pore Volume (cm³/g)1300.81 0.0523218876.882 0.109237674.35 0.138315364.14 0.206816

264.176 0.230416203.727 0.244078165.533 0.252638139.29 0.258453117.589 0.263312104.835 0.26615884.4336 0.27076270.4692 0.27395760.2416 0.27640452.4561 0.27836546.2595 0.27992641.1816 0.2813336.8929 0.282554

33.2554 0.28363230.1732 0.28461427.293 0.28566524.5676 0.28683722.2021 0.28801721.2757 0.28872620.3546 0.28932719.4049 0.290055






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BJH Adsorption dV/dD Pore VolumeHalsey : Faas Correction

Z-22- 15h_SAR90Pore Diameter (Å) Pore Volume (cm³/g·Å)1483.04 9.32246e-0051007.42 0.000134254748.787 0.000143576

431.206 0.000220822297.753 0.000236078225.717 0.000226017180.385 0.00022411149.946 0.000221573126.416 0.000223935110.392 0.0002231592.1644 0.00022568676.005 0.00022880264.4173 0.00023923255.7065 0.00025185648.885 0.00025196943.3559 0.000276361

38.741 0.000285534.8329 0.00029627431.5195 0.00031861628.5422 0.00036481325.7375 0.00043014523.2205 0.00049866921.7112 0.00076580420.7863 0.00065217619.8474 0.000766571






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Completed: 3/2/2016 9:01:19 Analysis Bath Temp.: -195.810





BJH Adsorption dV/dlog(D) Pore VolumeHalsey : Faas Correction

Z-22- 15h_SAR90Pore Diameter (Å) dV/dlog(D) Pore Volume (cm³/g·Å)1483.04 0.3358741007.42 0.332302

748.787 0.254951431.206 0.255967297.753 0.169322225.717 0.121073180.385 0.0949343149.946 0.0775662126.416 0.0660693110.392 0.057080592.1644 0.048986776.005 0.040693464.4173 0.035927655.7065 0.032625848.885 0.0285987

43.3559 0.0277938.741 0.025636834.8329 0.02390631.5195 0.023248628.5422 0.02411625.7375 0.025658923.2205 0.026828221.7112 0.03832720.7863 0.031252819.8474 0.035083





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BJH Adsorption Cumulative Pore AreaHalsey : Faas Correction

Z-22- 15h_SAR90Pore Diameter (Å) Pore Area (m²/g)1300.81 1.4112

876.882 3.67103674.35 5.22439364.14 11.5788264.176 14.7491203.727 17.1703165.533 19.0684139.29 20.6195117.589 22.1572104.835 23.188484.4336 25.186770.4692 26.868260.2416 28.387552.4561 29.7955

46.2595 31.073141.1816 32.367836.8929 33.63233.2554 34.869630.1732 36.115827.293 37.588324.5676 39.410322.2021 41.442321.2757 42.749420.3546 43.905419.4049 45.3726





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BJH Adsorption dA/dD Pore AreaHalsey : Faas Correction

Z-22- 15h_SAR90Pore Diameter (Å) Pore Area (m²/g·Å)

1483.04 0.002514411007.42 0.00533063748.787 0.00766976431.206 0.0204841297.753 0.0317146225.717 0.0400532180.385 0.0496961149.946 0.0591073126.416 0.0708567110.392 0.08085792.1644 0.097949276.005 0.12041464.4173 0.148552

55.7065 0.18084548.885 0.20617343.3559 0.25496938.741 0.29477834.8329 0.34022331.5195 0.40434128.5422 0.51126125.7375 0.66851223.2205 0.85901521.7112 1.4108920.7863 1.2550119.8474 1.54493




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BJH Adsorption dA/dlog(D) Pore AreaHalsey : Faas Correction

Z-22- 15h_SAR90

Pore Diameter (Å) dA/dlog(D) Pore Area (m²/g·Å)1483.04 9.059041007.42 13.1942748.787 13.6194431.206 23.7443297.753 22.7467225.717 21.4558180.385 21.0515149.946 20.6917126.416 20.9054110.392 20.682892.1644 21.260676.005 21.4161

64.4173 22.309355.7065 23.426948.885 23.400843.3559 25.638938.741 26.469934.8329 27.452231.5195 29.503728.5422 33.796925.7375 39.877923.2205 46.214821.7112 70.612320.7863 60.141119.8474 70.7055


Sample: Z-22- 15h_SAR90Operator: RAMIRO


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Submitter: MARITZA/OSIMARFile: C:\2020\DATA\000-560.SMP







BJH Desorption Pore Distribution Report

Faas Correction

Halseyt = 3.54 [ -5 / ln(P/Po) ] ^ 0.333

Diameter Range: 17.000 Å to 3000.000 ÅAdsorbate Property Factor: 9.53000 ÅDensity Conversion Factor: 0.0015468

Fraction of Pores Open at Both Ends: 0.00

Incremental CumulativeCumulative

Average Pore Pore Incremental

PorePore Diameter Diameter Volume Volume Pore AreaArea

Range (Å) (Å) (cm³/g) (cm³/g) (m²/g) (m²/g------ 1862.1 - 1605.5 1714.6 0.006561 0.006561 0.153

0.1531605.5 - 1390.2 1482.2 0.010017 0.016578 0.2700.4231390.2 - 984.8 1118.7 0.039465 0.056043 1.4111.835984.8 - 407.0 486.5 0.127571 0.183614 10.489

12.324

407.0 - 267.9 308.5 0.039616 0.223230 5.13617.460267.9 - 203.9 226.8 0.019115 0.242344 3.371

20.831203.9 - 163.5 179.0 0.011115 0.253459 2.484

23.315163.5 - 131.0 143.4 0.008165 0.261624 2.278

25.593131.0 - 114.2 121.3 0.004043 0.265667 1.333

26.926


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114.2 - 106.2 109.9 0.001869 0.267536 0.68027.607

106.2 - 84.2 92.4 0.005037 0.272573 2.18129.788

84.2 - 70.5 75.9 0.002912 0.275485 1.53431.321

70.5 - 60.5 64.6 0.002030 0.277514 1.25832.579

60.5 - 52.6 55.9 0.001609 0.279123 1.15233.731

52.6 - 46.3 48.9 0.001014 0.280137 0.82834.559

46.3 - 41.3 43.4 0.001044 0.281180 0.96135.520

41.3 - 36.9 38.8 0.000883 0.282064 0.91136.431

36.9 - 33.3 34.9 0.000780 0.282843 0.89437.326

33.3 - 30.0 31.4 0.000562 0.283405 0.71438.040

30.0 - 27.2 28.4 0.000451 0.283856 0.63438.674

27.2 - 24.6 25.7 0.000637 0.284493 0.99039.664

24.6 - 22.2 23.2 0.000881 0.285374 1.51841.18222.2 - 19.4 20.5 0.001203 0.286577 2.348

43.529


Sample: Z-22- 15h_SAR90Operator: RAMIRO

Submitter: MARITZA/OSIMARFile: C:\2020\DATA\000-560.SMP







BJH Desorption Cumulative Pore VolumeHalsey : Faas Correction


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Z-22- 15h_SAR90Pore Diameter (Å) Pore Volume (cm³/g)1605.53 0.006560821390.25 0.0165775984.758 0.0560428406.957 0.183614267.944 0.22323203.942 0.242344163.54 0.253459130.985 0.261624114.159 0.265667106.231 0.26753684.2258 0.27257370.4624 0.27548560.4535 0.27751452.6003 0.27912346.2745 0.28013741.2819 0.2811836.9141 0.28206433.2928 0.28284330.0369 0.28340527.2075 0.28385624.6119 0.284493

22.1729 0.28537419.3609 0.286577



File: C:\2020\DATA\000-560.SMPStarted: 2/2/2016 11:15:32 Analysis Adsorptive: N2






BJH Desorption dV/dD Pore VolumeHalsey : Faas Correction


24/28

Z-22- 15h_SAR90Pore Diameter (Å) Pore Volume (cm³/g·Å)1714.56 2.55759e-0051482.17 4.65272e-0051118.67 9.73277e-005486.491 0.000220787308.541 0.000284982226.812 0.000298657178.975 0.000275107143.352 0.000250797121.289 0.000240297109.874 0.0002356992.3808 0.00022890475.9365 0.00021155264.5607 0.00020279855.8756 0.00020487548.9457 0.00016022643.4262 0.00020901538.7913 0.00020224134.8646 0.00021528431.4472 0.000172528.4371 0.00015925125.7345 0.00024539923.2178 0.000361203

20.5002 0.000427912










BJH Desorption dV/dlog(D) Pore VolumeHalsey : Faas Correction

Z-22- 15h_SAR90


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Pore Diameter (Å) dV/dlog(D) Pore Volume (cm³/g·Å)1714.56 0.1019181482.17 0.1601971118.67 0.263519486.491 0.332405308.541 0.218265226.812 0.161254178.975 0.115922143.352 0.084694121.289 0.0677133109.874 0.059776792.3808 0.04996875.9365 0.03757664.5607 0.030506555.8756 0.026623148.9457 0.018214243.4262 0.021046538.7913 0.018188134.8646 0.017385731.4472 0.012566128.4371 0.010486925.7345 0.014628123.2178 0.019437820.5002 0.0204304




Started: 2/2/2016 11:15:32 Analysis Adsorptive: N2Completed: 3/2/2016 9:01:19 Analysis Bath Temp.: -195.810





BJH Desorption Cumulative Pore AreaHalsey : Faas Correction

Z-22- 15h_SAR90Pore Diameter (Å) Pore Area (m²/g)


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1605.53 0.1530611390.25 0.423386984.758 1.83454406.957 12.3236267.944 17.4595203.942 20.8305163.54 23.3147130.985 25.5929114.159 26.9263106.231 27.606684.2258 29.787670.4624 31.321360.4535 32.578952.6003 33.730746.2745 34.55941.2819 35.520236.9141 36.431133.2928 37.325530.0369 38.039927.2075 38.673724.6119 39.663822.1729 41.181519.3609 43.5294










BJH Desorption dA/dD Pore AreaHalsey : Faas Correction

Z-22- 15h_SAR90Pore Diameter (Å) Pore Area (m²/g·Å)1714.56 0.000596674


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1482.17 0.001255651118.67 0.00348012486.491 0.0181534308.541 0.0369458226.812 0.0526703178.975 0.0614852143.352 0.0699809121.289 0.0792476109.874 0.085803692.3808 0.099113375.9365 0.11143764.5607 0.12564855.8756 0.14666548.9457 0.13094243.4262 0.19252538.7913 0.20854234.8646 0.24699531.4472 0.21941528.4371 0.22400425.7345 0.38143123.2178 0.62228720.5002 0.834943





Completed: 3/2/2016 9:01:19 Analysis Bath Temp.: -195.810 °CReport Time: 2/3/2016 9:42:39 Thermal Correction: No




BJH Desorption dA/dlog(D) Pore AreaHalsey : Faas Correction

Z-22- 15h_SAR90Pore Diameter (Å) dA/dlog(D) Pore Area (m²/g·Å)1714.56 2.37771482.17 4.32329


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1118.67 9.42259486.491 27.3309308.541 28.2965226.812 28.4384178.975 25.908143.352 23.6325121.289 22.3311109.874 21.761992.3808 21.635675.9365 19.793464.5607 18.90155.8756 19.058948.9457 14.885343.4262 19.38638.7913 18.754834.8646 19.946531.4472 15.983728.4371 14.75125.7345 22.736923.2178 33.487820.5002 39.8638

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