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    Preliminary Investigation of OBDBr-2Catalyst Monitor Performance with

     Aftermarket Catalysts

    Michel Zambon Alves – Ford Motor Company Brasil

     Alan Arnhem – Umicore Automotive Catalyst

    Paul Baltusis – Ford Motor Company Brasil

    Eduardo Burgos – Ford Motor Company BrasilClayton Orasmo – Umicore Automotive Catalyst

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    Main Topics

    Motivation  Aftermarket catalyst requirements

    Catalyst monitor principals

    Theoretical analysis: risk of MIL activation

    Experimental analysis: catalyst monitor performance

    Conclusions

    Future Developments

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    Motivation

    Implementation of OBDBr-2 starting in 2010

    INMETRO – Aftermarket Catalytic Converter Report:

    5 of 11 samples rejected in the visual inspection (empty cans)

    6 samples approved according to Conama 282/2001

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    CONAMA Resolution 354/2004

    general requirements

    implementation phase-in

    OBDBr-1

    OBDBr-2

    Regulatory Instructions

    detailed technicalrequirements

    OBDBr-1: 126/2006

    OBDBr-2: 24/2009

    2010 201160% 100%

    2007 2008 2009

    40% 70% 100%

    OBDBr Regulations

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    Summary of Aftermarket Catalyst

    Regulatory Requirements

    Catalytic converter

    40,000 miles aged

    NBR-6601 cycle

    Catalytic converters and

    oxygen sensors 50,000miles agedEPA-75 cycle

    not aged

    Type I cycle

    Not specified5 yearswarranty rates > 4% rescission

    Not specifiedWarranty

    Not specifiedCatalysts aged to the pointof MIL illumination.1.5 times the malfunctionthresholds as required forOEM OBD certification (all

    pollutants).

    Catalysts aged to the pointof MIL illumination.Same malfunction thresholdsas required for OEM OBDcertification (Euro IV: THC;

    Euro V: NMHC, NOx)

    OBD

    Conversion efficiencies:CO (70%)HC (70%)

    NOx (60%)

    Full useful life certificationstandard

    aftermarket vs originalcatalyst configuration:M ≤ G

    M≤

    0.85 S + 0.4 G

    Base

    tailpipeemissions

    BrazilUnited States (ARB)European Union

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    Oxygen Storage Principals

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    Catalyst Monitor Principals

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    Theoretical analysisRisk of MIL activation with aftermarket catalysts

    TP = 0.3 g/km (OBDBr-2 malfunction threshold for NMHC)

    EFF = 70% (min. acceptable HC conversion eff. for aftermarket catalysts)

    Typical values of PRE NMHC (PROCONVE L-5) higher than 1.0 g/km

    PRE 

    TPPRE  EFF 

      −=

     EFF 

    TPPRE 

    =

    1

    kmgPRE  NMHC    / 0.1<

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    Tested Samples:

    BASELINE - original Ford Motor Company 80k aged catalyst

    CATALYST 1 - Umicore standard aftermarket 40k aged catalyst

    (OSC at lower limit specification)

    CATALYST 2 - Umicore standard aftermarket 40k aged catalyst

    (OSC at nominal limit specification)

    THRESHOLD - original Ford Motor Company part aged to the point

    of MIL illumination

    Experimental Analysis

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    2 NBR-6601 per sample Rocam 1.6L Flex vehicle (PL5 compliant)

    Measurements:

    Tailpipe emissions (NMHC) Conversion Efficiency (THC)

    Calculated catalyst index ratio (IR)

    Experimental Analysis

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    HC Conversion Eff vs IR - E100

    0.000

    0.100

    0.200

    0.300

    0.400

    0.500

    0.600

    0.700

    0.800

    0.900

    40.0% 50.0% 60.0% 70.0% 80.0% 90.0% 100.0%

    EFF HC %

       C  a   t  a   l  y  s   t   I  n   d  e  x   R  a   t   i

    BASELINE AFTERMARKET 1 AFTERMARKET 2 THRESHOLD Linear

    HC Conversion Eff vs IR - E22

    0.000

    0.100

    0.200

    0.300

    0.400

    0.500

    0.600

    0.7000.800

    0.900

    40.0% 50.0% 60.0% 70.0% 80.0% 90.0% 100.0%

    EFF HC %

       C  a   t  a   l  y  s   t   I  n   d  e  x   R  a   t   i

    BASELINE AFTERMARKET 1 AFTERMARKET 2 THRESHOLD Linear

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    NMHC vs IR - E22

    0.000

    0.100

    0.200

    0.300

    0.400

    0.500

    0.600

    0.700

    0.800

    0.900

    0.000 0.020 0.040 0.060 0.080 0.100 0.120 0.140 0.160 0.180

    NMHC

       C  a   t  a   l  y  s   t   I  n   d  e  x   R  a   t

       i

    BASELINE AFTERMARKET 1 AFTERMARKET 2 THRESHOLD Linear

    NMHC vs IR - E100

    0.000

    0.100

    0.200

    0.3000.400

    0.500

    0.600

    0.700

    0.800

    0.900

    0.000 0.020 0.040 0.060 0.080 0.100 0.120 0.140 0.160 0.180

    NMHC

       C  a   t  a   l  y  s   t

       I  n   d  e  x   R  a   t   i

    BASELINE AFTERMARKET 1 AFTERMARKET 2 THRESHOLD Linear

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    Experimental Results

    CATALYST

    INDEX RATIO NMHC [g/km]

    THC

    CONVERSION

    EFFICIENCY

    CATALYST

    INDEX RATIO NMHC [g/km]

    THC

    CONVERSION

    EFFICIENCY

    BASELINE

    CATALYSTref ref ref ref ref ref

    AFTERMARKET 28% 95% -4% 44% 25% -14%

    THRESHOLD

    CATALYST515% 170% -7% 605% 222% -43%

    E22 E100

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    Conclusions

    Brazilian regulations for aftermarket catalysts are much lessstringent than those for Europe or the US for both tailpipe

    emissions and OBD. Specifically for OBD, there is no regulatoryrequirement in Brazil.

    The tested aftermarket catalysts were able to comply with theapplicable emission regulatory requirements.

    The probability of premature MIL activation for the testedUmicore aftermarket catalysts 1 and 2 is very low.

    Lots of efforts are being spent on OEM emissions legislation(PL6, OBDBr-2 etc), but the regulation for aftermarketemission control devices has not been updated accordingly.

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    Future Developments

    It is important to analyze a wider and more representative

    sample of aftermarket catalytic converters from differentsuppliers in order to better understand the real probability ofpremature MIL activation in the field as well as to helpdefine future Brazilian OBD regulation for aftermarket

    catalysts.

    Continue investigating the trade-offs between oxygenstorage and washcoat mass as it affects catalyst light-off

    time and NMHC emissions for fuels ranging from E22 toE100.

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    Thank you!

    Regulatory information contained in this paper is intended to serve as a reference only.

    The latest rules and regulations must be used for official testing / development.